Can you figure out what this is?!?!?!?

if you can figure out which character this is and from what epuisode of Bleach, i'll draw something for you and 5 of my suscribers.(don't expect anything too fancy!)
not much but haha

i'll even guve you a hint
its just how nice i am

He turns into a large bull with exclamation

hahahah
good hint, no?

good luck

End